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The nine England players who have reached 100 caps will be honoured ahead of Sunday's Euro 2017 qualifier against Bosnia and Herzegovina.
The group, which includes current squad members Casey Stoney, Fara Williams and Jill Scott, will receive a special cap from Uefa before the game in Bristol.
"To join the 100 club is a fantastic achievement for any player," said England head coach Mark Sampson.
The game will be England's first at home since this summer's World Cup.
It is their second qualifying game of their Euro 2017 campaign, having won their first 8-0 in Estonia.
Sunday's match will be shown live on BSports Two from 15:15 GMT.
England's centurions |
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Fara Williams (147 caps), Rachel Yankey (129), Alex Scott (129), Casey Stoney (123), Gill Coultard (119), Kelly Smith (117), Karen Carney (110), Rachel Unitt (102), Jill Scott (100). |
Sampson's side finished third at the World Cup in Canada, their best ever showing in the competition.
Scott is the most recent player to reach 100 caps, reaching the milestone in a 1-0 win against Australia in October at the International Women's Football Tournament in Yongchuan, China.
The other England players to have passed a century of international appearances are Rachel Yankey, Alex Scott, Gill Coultard, Kelly Smith, Karen Carney and Rachel Unitt.
Fans are being invited to take part in a parade along the route the team coach will take before the game to welcome the team back to the country following their achievements at the World Cup.
After the parade, young supporters will also be able to visit a free FA Junior Fanzone outside the stadium, which starts at 13:30 GMT.
"These events are great at building the atmosphere ahead of kick off and offer lots of fun activities for fans to try," said FA women's football national project officer Polly Fildes.
Goalkeepers: Karen Bardsley (Manchester City), Rachael Laws (Sunderland), Carly Telford (Notts County)
Defenders: Laura Bassett (Notts County), Lucy Bronze (Manchester City), Gilly Flaherty (Chelsea), Alex Greenwood (Notts County), Steph Houghton (Manchester City), Jemma Rose (Arsenal), Demi Stokes (Manchester City), Casey Stoney (Arsenal), Amy Turner (Notts County)
Midfielders: Isobel Christiansen (Manchester City), Jordan Nobbs (Arsenal), Jill Scott (Manchester City), Fara Williams (Liverpool)
Forwards: Eni Aluko (Chelsea), Jess Clarke (Notts County), Gemma Davison (Chelsea), Toni Duggan (Manchester City), Fran Kirby (Chelsea), Jodie Taylor (Portland Thorns), Ellen White (Notts County)